absolute reaction rate theory

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• absolute reaction rate — The reaction rate determined from statistical thermodynamics; uses the assumption of the theory of absolute reaction rates that the rate of a chemical reaction is governed by the rate of crossing an energy barrier or of forming an activated… …   Dictionary of automotive terms

• reaction mechanism — Introduction       in chemical reactions (chemical reaction), the detailed processes by which chemical substances are transformed into other substances. The reactions themselves may involve the interactions of atoms (atom), molecules (molecule),… …   Universalium

• Collision theory — Reaction rate tends to increase with concentration phenomenon explained by collision theory Collision theory is a theory proposed by Max Trautz[1] and William Lewis in 1916 and 1918, that qualitatively explains how chemical reactions occur and… …   Wikipedia

• Marcus theory — is a theory originally developed by Rudolph A. Marcus, starting in 1956, to explain the rates of electron transfer reactions – the rate at which an electron can move or jump from one chemical species (called the electron donor) to another (called …   Wikipedia

• electrochemical reaction — ▪ chemistry Introduction       any process either caused or accompanied by the passage of an electric current and involving in most cases the transfer of electrons between two substances one a solid and the other a liquid.       Under ordinary… …   Universalium

• Cheletropic reaction — Pericyclic Reactions Cheletropic reactions are a type of pericyclic reaction. A pericyclic reaction is one that involves a transition state with a cyclic array of atoms and an associated cyclic array of interacting orbitals. A reorganization of σ …   Wikipedia

• Proton transfer reaction - mass spectrometry — (PTR MS) is a very sensitive technique for online monitoring of volatile organic compounds (VOCs) in ambient air developed by scientists at the Institut für Ionenphysik at the Leopold Franzens University in Innsbruck, Austria [A. Hansel, A.… …   Wikipedia

• transition-state theory — ▪ chemistry also called  activated complex theory, or theory of absolute reaction rates   a treatment of chemical reactions (chemical reaction) and other processes that regards them as proceeding by a continuous change in the relative positions… …   Universalium

• HSAB theory — The HSAB concept is an acronym for hard and soft (Lewis) acids and bases. Also known as the Pearson acid base concept, HSAB is widely used in chemistry for explaining stability of compounds, reaction mechanisms and pathways. It assigns the terms… …   Wikipedia

• probability theory — Math., Statistics. the theory of analyzing and making statements concerning the probability of the occurrence of uncertain events. Cf. probability (def. 4). [1830 40] * * * Branch of mathematics that deals with analysis of random events.… …   Universalium

• Nobel Prizes — ▪ 2009 Introduction Prize for Peace       The 2008 Nobel Prize for Peace was awarded to Martti Ahtisaari, former president (1994–2000) of Finland, for his work over more than 30 years in settling international disputes, many involving ethnic,… …   Universalium